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By Ana M. Garcia-Campana

Discusses static recommendations and flowing circulate measurements of chemiluminscence utilized to chemical research, with studies of advances in immunoassay thoughts and makes use of of enzyme reactions. comprises attention of a number purposes in analytical study, biotechnology and chemical quality controls.

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These mechanisms refer to the term ‘‘sensitized’’ CL. Chandross in 1963 [85] and McKeown and Waters in 1964 [86] observed the visible light emitted during the reaction of hydrogen peroxide with oxalyl chloride or certain nitriles. Hercules [87] and Visco and Chandross [88] independently reported the visible production of light generated in the vicinity of the cathode when a series of highly condensed aromatic hydrocarbons were electrolyzed in acetonitrile or dimethylformamide with tetraethylammonium salts employed as supporting electrolytes.

106. CLR Catherall, TF Palmer, RB Cundall. J Chem Soc Faraday Trans 80:823–834, 1984. 107. CLR Catherall, TF Palmer, RB Cundall. J Chem Soc Faraday Trans 80:837–849, 1984. 108. FL Alva´rez, JP Parekh, B Matusewski, RS Givens, T Higuchi, RL Schowen. J Am Chem Soc 108:6435–6437, 1986. 109. N Hanaoka, RS Givens, RL Schowen, T Kuwana. Anal Chem 60:2193–2197, 1988. 110. F McCapra, A Burford. J Chem Soc Chem Commun 607, 1976. 111. JY Koo, GB Schuster. J Am Chem Soc 99:6107, 1977. 112. JY Koo, GB Schuster.

Chandross and Sonntag [89] found a similar behavior when chemically produced aromatic radical anions were reacted with electron acceptors such as 9,10-dichloro-9,10-diphenyl-9,10-dihydroanthracene, benzoyl peroxide, oxalyl chloride, mercuric chloride, and aluminum chloride. Throughout the 1960s and 1970s there was much interest in these phenomena for studying new compounds, the different mechanisms, and the nature of the emitting state. In particular, polyaromatic hydrocarbons and their derivatives, ruthenium, osmium, platinum, palladium, and other transition metal complexes, and molybdenum and tungsten clusters have been studied in relation to their photochemical and electrochemical properties.

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